I study on Gene expression, Molecular proliferation and Cellular signalling on photosynthetic activities of Piper nigrum L. grows up for cash crops verdict importance. A vigorous campaign exercise of Photosynthetic pigmentations development happen such as Chlorophyll a b Xanthophylls carotenoids dominance characteristics features which excited by solar energy purses with Cyper electron transport from Hydrogen proton which shared Cyper electron transport to Mg2 attachment of Chlorophyll a b Xanthophylls carotenoids pigmentations siganlling enshown along with the strength of mRNA expression interests depending on rRNA decodes tRNA genetic informations codes from Polyribosomes involved in Biosynthesis of enzymic proteins activities in relation with Plant Genetics of DNA genomic loci for the production of Photosynthetic products using the immediate response of mitochondrial ATP production process from Glucose molecules from Chloroplasts mobilization used to be enhanced by means of micronutritional effect of ZnSO4 optimum effect which could produce Zn+ and SO4- ionic equilibrium as Bioelectrolysis cellular activities and Bioelectricity & Biomagnetic fieldstones operation involvement in the establishment of Bioelectronics ZnSO4 optimum effect on Piper nigrum L.